AGS-Energy
Building a new World with environmentally clean and renewable energy technologies
Hydrogen Economy Electrochemical extraction of energy from hydrogen via fuel cells is an especially clean method of meeting power requirements, but not an efficient one, due to the necessity of adding large amounts of energy to either water or hydrocarbon fuels in order to produce the hydrogen. Additionally, during the extraction of hydrogen from hydrocarbons, carbon monoxide is released. Although this gas is artificially converted into carbon dioxide, such a method of extracting hydrogen remains environmentally injurious. Also, it must be noted that regarding the concept of the hydrogen vehicle, burning/combustion of hydrogen in an internal combustion engine (IC/ICE) is often confused with the electrochemical process of generating electricity via fuel cells (FC) in which there is no combustion (though there is a small byproduct of heat in the reaction). Both processes require the establishment of a hydrogen economy before they may be considered commercially viable, and even then, the aforementioned energy costs make a hydrogen economy of questionable environmental value. Hydrogen combustion is similar to petroleum combustion, and like petroleum combustion, still results in nitrogen oxides as a by-product of the combustion, which lead to smog. Hydrogen combustion, like that of petroleum, is limited by the Carnot efficiency, and is completely different from the hydrogen fuel cell's chemical conversion process of hydrogen to electricity and water without combustion. Hydrogen fuel cells emit only water during use, while producing carbon dioxide emissions during the majority of hydrogen production, which comes from natural gas. Direct methane or natural gas conversion (whether IC or FC) also generate carbon dioxide emissions, but direct hydrocarbon conversion in high-temperature fuel cells produces lower carbon dioxide emissions than either combustion of the same fuel (due to the higher efficiency of the fuel cell process compared to combustion), and also lower carbon dioxide emissions than hydrogen fuel cells, which use methane less efficiently than high-temperature fuel cells by first converting it to high purity hydrogen by steam reforming. Although hydrogen can also be produced by electrolysis of water using renewable energy, at present less than 3% of hydrogen is produced in this way. Hydrogen is an energy carrier, and not an energy source, because it must be produced by adding energy from other energy sources, such as fossil fuels, wind power, nuclear power, or solar photovoltaic cells. Hydrogen may be produced from subsurface reservoirs of methane and natural gas by a combination of steam reforming with the water gas shift reaction, from coal by coal gasification, or from oil shale by oil shale gasification. low pressure electrolysis of water or high pressure electrolysis, which requires electricity, and high-temperature electrolysis/thermochemical production, which requires high temperatures (ideal for the expected Generation IV reactors), are two primary methods for the extraction of hydrogen from water. As of 2006, 49.0% of the electricity produced in the United States comes from coal, 19.4% comes from nuclear, 20.0% comes from natural gas, 7.0% from hydroelectricity, 1.6% from petroleum and the remaining 3.1% mostly coming from geothermal, solar and biomass. When hydrogen is produced through electrolysis, the energy comes from these sources. Though the fuel cell itself will only emit heat and water as waste, pollution is often caused when generating the electricity required to produce the hydrogen that the fuel cell uses as its power source (for example, when fossil fuel-generated electricity is used). This will be the case unless the hydrogen is produced using electricity generated by hydroelectric, geothermal, solar, wind or other clean power sources (which may or may not include nuclear power, depending on one's attitude to the nuclear waste byproducts); hydrogen is only as clean as the energy sources used to produce it. A holistic approach has to take into consideration the impacts of an extended hydrogen scenario, including the production, the use and the disposal of infrastructure and energy converters. Nowadays low temperature fuel cell stacks proton exchange membrane fuel cell (PEMFC), direct methanol fuel cell (DMFC) and phosphoric acid fuel cell (PAFC) make extensive use of platinum catalysts. Impurities create catalyst poisoning (reducing activity and efficiency) in these low-temperature fuel cells, thus high hydrogen purity or higher catalyst densities are required. Although platinum is seen by some as one of the major ''showstoppers'' to mass market fuel cell commercialization companies, most predictions of platinum running out and/or platinum prices soaring do not take into account effects of thrifting (reduction in catalyst loading) and recycling. Recent research at Brookhaven National Laboratory could lead to the replacement of platinum by a gold-palladium coating which may be less susceptible to poisoning and thereby improve fuel cell lifetime considerably. Current targets for a transport PEM fuel cells are 0.2 g/kW Pt – which is a factor of 5 decrease over current loadings – and recent comments from major original equipment manufacturers (OEMs) indicate that this is possible. Also it is fully anticipated that recycling of fuel cells components, including platinum, will kick in. High-temperature fuel cells, including molten carbonate fuel cells (MCFC's) and solid oxide fuel cells (SOFC's), do not use platinum as catalysts, but instead use cheaper materials such as nickel and nickel oxide, which are considerably more abundant (for example, nickel is used in fairly large quantities in common stainless steel). They also do not experience catalyst poisoning by carbon monoxide, and so they do not require high-purity hydrogen to operate. They can use fuels with an existing and extensive infrastructure, such as natural gas, directly, without having to first reform it externally to hydrogen and CO followed by CO removal. Instead, they can more efficiently use the same fuels that are used to make hydrogen for low-temperature fuel cells. This fuel flexibility, combined with new developments to make SOFCs on cheaper and more durable metal supports, makes SOFCs increasingly important as candidates for transportation, as well as for stationary power. SOFCs have the highest efficiency of all fuel cell types, and their ability to use common fuels, including liquid fuels, may make them more suitable for long-distance vehicular transportation, as well as for stationary power. |
